60.0.13
Page 1/9
Safety data sheet according to UK REACH Printing date 18.12.2024
Version number 4 (replaces version 3)
Revision: 18.12.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-GH-S (B-Komp.) · UFI: RVJU-1WU4-M508-43H2 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Reaction resin · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 STOT SE 3
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. (Contd. on page 2) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 1)
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07, GHS08 · Signal word Danger · Hazard-determining components of labelling: diphenylmethanediisocyanate,isomeres and homologues · Hazard statements H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P281 Use personal protective equipment as required. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: EUH204 Contains isocyanates. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Produkt based on polyisocyanate. · Dangerous components: CAS: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 50-100% Index number: 615-005-00-9 Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335, EUH204 Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % Skin Irrit. 2; H315: C ≥ 5 % Resp. Sens. 1; H334: C ≥ 0.1 % STOT SE 3; C ≥ 5 % · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). (Contd. on page 3) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 2)
Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Carbon monoxide (CO) Nitrogen oxides (NOx) Hydrogen cyanide (HCN) Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear full protective suit. Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. (Contd. on page 4) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 3)
See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in unopened original containers. The Product reacts with water and CO2-Gas will be given off. In tight closed containers pressure may arise and the cover can burst. · Information about storage in one common storage facility: Store away from water. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Store under dry conditions. Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (50-100%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO · Regulatory information WEL: EH40/2020 · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Hand protection PVC gloves Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. (Contd. on page 5) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 4)
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves PVC gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Gloves made of: Nitrile rubber, butyl rubber. (Category 3 chemical protective gloves, recognisable by the CE mark with four-digit test number). When wearing protective gloves, cotton undergloves are recommended. Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable: PVC gloves · For the permanent contact gloves made of the following materials are suitable: PVC gloves · For the permanent contact of a maximum of 15 minutes gloves made of the following materials are suitable: PVC gloves · As protection from splashes gloves made of the following materials are suitable: PVC gloves · Not suitable are gloves made of the following materials: PVC gloves Leather gloves Strong gloves · Eye/face protection Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Various colours · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range >200 °C · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: >100 °C · Auto-ignition temperature: 530 °C · Decomposition temperature: Not determined. · pH Mixture reacts violently with water. · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 160 mPas (Contd. on page 6) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 5)
· Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Not miscible or difficult to mix Not determined. Not determined. 1.12 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Harmful if inhaled. (Contd. on page 7) GB
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 6)
· LD/LC50 values that are relevant for classification: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues Oral LD50 >10,000 mg/kg (rats) (OECD 401) Dermal LD50 >9,400 mg/kg (rabbit) (OECD 402) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. · Carcinogenicity Suspected of causing cancer. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues EC 50 >1,000 mg/kg (dam) (OECD 202 (24 h)) >1,640 mg/kg (Grünalge (Scenedesmus subspicatus)) (OECD 201) LC50/96h >1,000 mg/l (zebra danio) (OECD 203) EC50 (3h) >100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) ERC50 >1,640 mg/l (Grünalge (Scenedesmus subspicatus)) (OECD 201 (72 h)) NOEC >1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) >1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) >1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) NOEC >10 mg/l (dam) (OECD 202 (21 d)) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water danger class 3 (Self-assessment): extremely hazardous for water. Do not allow product to reach ground water, water bodies or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into soil. GB
(Contd. on page 8)
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 7)
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · National regulations · Technical instructions (air): · Class Share in % · I 75.0 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB
(Contd. on page 9)
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Trade name: ASODUR-GH-S (B-Komp.) (Contd. of page 8)
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. EUH204 Contains isocyanates. May produce an allergic reaction. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Resp. Sens. 1: Respiratory sensitisation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Carc. 2: Carcinogenicity – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
· * Data compared to the previous version altered. GB