60.0.21
Page 1/11
Safety data sheet according to UK REACH Printing date 14.01.2025
Version number 35
Revision: 07.01.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-K900 (B-Komp.) · UFI: G8X9-1KWH-6008-WW2G · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 *
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Repr. 2
H361d Suspected of damaging the unborn child. GHS05 corrosion
Skin Corr. 1B Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. (Contd. on page 2) GB
Page 2/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 1)
GHS07 Acute Tox. 4 Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H332 Harmful if inhaled. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07, GHS08, GHS09 · Signal word Danger · Hazard-determining components of labelling: benzyl alcohol 4,4'Isopropylendiphenol, oligomeric reaction products with 1- chlorine-2,3-epoxypropane reaction products -phenylenbis (methylamine) salicylic acid m-phenylenebis(methylamine) 3-aminomethyl-3,5,5-trimethylcyclohexylamine phenol · Hazard statements H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H361d Suspected of damaging the unborn child. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dusts or mists. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. · Additional information: EUH071 Corrosive to the respiratory tract. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below and non-hazardous additions. (Contd. on page 3) GB
Page 3/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 2)
· Dangerous components: CAS: 100-51-6 benzyl alcohol 25-50% EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319; Index number: 603-057-00-5 Skin Sens. 1B, H317 ATE: LD50 oral: 1,200 mg/kg 10-25%
CAS: 113930-69-1
4,4'Isopropylendiphenol, oligomeric reaction products with 1chlorine-2,3-epoxypropane reaction products -phenylenbis (methylamine) Skin Corr. 1B, H314; Eye Dam. 1, H318; Aquatic Skin Sens. 1, H317 Chronic 2, H411;
CAS: 1477-55-0 EINECS: 216-032-5
m-phenylenebis(methylamine) 10-25% Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1B, H317; Aquatic Chronic 3, H412, EUH071
CAS: 61788-44-1 EINECS: 262-975-0
phenol Aquatic Chronic 2, H411; 1, H317
10-25% Skin Irrit. 2, H315; Skin Sens.
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 2.5-10% EINECS: 220-666-8 Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, Index number: 612-067-00-9 H302; Acute Tox. 4, H312; Skin Sens. 1A, H317 ATE: LD50 oral: 1,030 mg/kg Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.001 % CAS: 69-72-7 salicylic acid EINECS: 200-712-3 Repr. 2, H361d; Eye Dam. 1, H318; Acute Tox. 4, Index number: 607-732-00-5 H302 · Additional information For the wording of the listed hazard phrases refer to section 16.
3-10%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Instantly call for doctor. (Contd. on page 4) GB
Page 4/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 3)
Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Use neutralising agent. Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. (Contd. on page 5) GB
Page 5/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 4)
· 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Self-contained breathing apparatus must be used in case of bad fresh-air-supply or no adequate removal suction is available. In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection Tightly sealed safety glasses. Suitable eye protection: Basket goggles. (DIN EN 166) Suitable safety goggles in accordance with DIN EN 166. In case of splashing use protecting basket-glasses. · Body protection: Acid resistant protective clothing Alkaline resistant protective clothing Apron Protective work clothing. (Contd. on page 6) GB
Page 6/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 5)
Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: Colourless · Smell: Amine-like · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: 94 °C · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 110-160 mPas · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density at 20 °C 1.06 g/cm³ · Relative density Not determined. · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids
Void Void Void Void Void Void Void Void Void Void (Contd. on page 7) GB
Page 7/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 6)
· Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Harmful if swallowed or if inhaled. · LD/LC50 values that are relevant for classification: 100-51-6 benzyl alcohol Oral LD50 1,200 mg/kg (ATE) 1,040 mg/kg (mouse) 1,620 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rabbit) Inhalative LC50 4.178 mg/l (rats) (OECD 403) 1477-55-0 m-phenylenebis(methylamine) Oral LD50 930 mg/kg (rats) (OECD 401) Dermal LD50 >3,100 mg/kg (rabbit) (OECD 402) Inhalative LC50 2.4 mg/l (not defined) 61788-44-1 phenol Oral LD50 >2,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1,030 mg/kg (ATE) 1,030 mg/kg (rats) (OECD 401) Dermal LD50 1,840 mg/kg (rabbit) >2,000 mg/kg (rats) 69-72-7 salicylic acid Oral LD50 891 mg/kg (rats) (OECD 401) Dermal LD50 >10,000 mg/kg (Kan) (OECD 402) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. (Contd. on page 8) GB
Page 8/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 7)
· Respiratory or skin sensitisation May cause an allergic skin reaction. · Reproductive toxicity Suspected of damaging the unborn child. · Additional toxicological information: Sensitizing · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 100-51-6 benzyl alcohol EC 50 390 mg/kg /(24h) (Pseudomas putida) LC50/96h 460 mg/l (Pimephales promelas) (EPA OPP 72-1) 645 mg/l (orfe) EC10 >658 mg/l /16h (Pseudomas putida) (DIN 38412) EC50 (48h) 230 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) (static) 770 mg/l (Pseudokirchneriella subcapitata) (OECD 201) NOEC 51 mg/l /21d (Daphnia magna) (OECD 211) 310 mg/l (Pseudokirchneriella subcapitata) (OECD 201) 1477-55-0 m-phenylenebis(methylamine) LC50/96h 87.6 mg/l (fish toxicity) >100 mg/l (for) >100 mg/l (Danio rerio) EC50 (48h) 15.2 mg/l (Daphnia magna) EC/LC50 (72h) 20.3 mg/l (algae toxicity) 61788-44-1 phenol EC50 (48h) EC/LC50 (72h) LL50
1-10 mg/l (Daphnia magna) 3.14 mg/l (Scenedesmus subspicatus) 14.8 mg/l (fish toxicity)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine LC50/96h 110 mg/l (Leuciscus idus) (OECD 203) EC50 (48h) 23 mg/l (Daphnia magna) (OECD TG 202) EC/10/18h 1,120 mg/l (Pseudomas putida) (Bringmann and Kühn 10, 87-98 (1977)) ERC50 >50 mg/l (Scenedesmus subspicatus) (EG 88/302 (72h)) 69-72-7 salicylic acid LC50/96h 1,380 mg/l (fish toxicity) EC50 (48h) 870 mg/l (Daphnia magna) EC/LC50 (72h) >100 mg/l (algae toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Remark: Toxic for fish (Contd. on page 9) GB
Page 9/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 8)
· Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. Danger to drinking water if even small quantities leak into soil. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG, IATA
UN2735 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. (4,4'Isopropylendiphenol, oligomeric reaction products with 1- chlorine-2,3-epoxypropane reaction products -phenylenbis (methylamine), benzyl alcohol), ENVIRONMENTALLY HAZARDOUS POLYAMINES, LIQUID, CORROSIVE, N.O.S. (4,4'Isopropylendiphenol, oligomeric reaction products with 1- chlorine-2,3-epoxypropane reaction products -phenylenbis (methylamine), benzyl alcohol)
· 14.3 Transport hazard class(es) · ADR, IMDG
· Class · Label
8 Corrosive substances. 8
· IATA
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards:
Product contains environmentally hazardous substances: 4,4'Isopropylendiphenol, oligomeric reaction products with 1- chlorine-2,3-epoxypropane (Contd. on page 10) GB
Page 10/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 9)
· · Marine pollutant: · Special marking (ADR):
reaction products -phenylenbis (methylamine) No Symbol (fish and tree) Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups · Stowage Category · Segregation Code
Warning: Corrosive substances. 80 F-A,S-B (SGG18) Alkalis A SG35 Stow "separated from" SGG1-acids
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 2 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. (4,4'ISOPROPYLENDIPHENOL, OLIGOMERIC REACTION PRODUCTS WITH 1CHLORINE-2,3-EPOXYPROPANE REACTION PRODUCTS -PHENYLENBIS (METHYLAMINE), BENZYL ALCOHOL), 8, II, ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t (Contd. on page 11) GB
Page 11/11
Trade name: ASODUR-K900 (B-Komp.) (Contd. of page 10)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H361d Suspected of damaging the unborn child. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative ATE: Acute toxicity estimate values Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Skin Sens. 1B: Skin sensitisation – Category 1B Repr. 2: Reproductive toxicity – Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB