60.0.21
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Safety data sheet According to 91/155 EEC Date of issue: 23.01.2025
Version number 33
Revision: 23.01.2025
1 Identification of the substance/mixture and of the company/undertaking · Other means of identification · Trade name: ASODUR-K4031 (B-Komp.) · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Hardening agent/ Curing agent · Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de Department: Environment & Safety · Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 2 Hazards identification · Classification of the substance or mixture GHS08 health hazard Carc. 2
H351 Suspected of causing cancer. Route of exposure: Inhalation. GHS05 corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. Acute Tox. 5 H303 May be harmful if swallowed. (Contd. on page 2) RU
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 1)
· Label elements · GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). · Hazard pictograms GHS05, GHS07, GHS08 · Signal word Danger · Hazard-determining components of labelling: benzyl alcohol 3-aminomethyl-3,5,5-trimethylcyclohexylamine titanium dioxide triethylenetetramine Phenol, 4,4-(1-methylethylidene)bis-, polymer with N,N-bis(2-aminoethyl)-1,2-ethanediamine and (chloromethyl)oxirane · Hazard statements May be harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of causing cancer. Route of exposure: Inhalation. · Precautionary statements Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. · Other hazards Not anwendbar. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Composition/information on ingredients · Chemical characterisation: Mixtures · Description: modified polyamidoamine · Dangerous components: CAS: 100-51-6 benzyl alcohol EINECS: 202-859-9 Acute Tox. 4, H302; Serious eye damage/irritation – Category 2A, H319; Skin Sens. 1, H317 PDK: Long-term value: 5 mg/m³ State: п Hazard class: 3 Body: + CAS: 112-24-3
triethylenetetramine Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412 PDK: Long-term value: 0,3 mg/m³ State: п+а Hazard class: 2 Body: A, +
2,5-10%
0-10%
(Contd. on page 3) RU
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 2)
CAS: 2855-13-2 EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 0-10% Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317 Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0,001 %
CAS: 68609-08-5 Reaction products of 3-aminomethyl-3,5,5-trimethylcyclohexylamine 0-<2,5% EC number: 614-657-1 with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] bisoxirane Acute Tox. 4, H302; Acute Tox. 5, H313 CAS: 38294-69-8
CAS: 13463-67-7
Phenol, 4,4-(1-methylethylidene)bis-, polymer with N,N-bis(20-<1% aminoethyl)-1,2-ethanediamine and (chloromethyl)oxirane Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Sens. 1, H317
titanium dioxide Carc. 2, H351; Acute Tox. 5, H333 PDK: Long-term value: 10 mg/m³ State: a Hazard class: 4 Body: Ф · Additional information For the wording of the listed hazard phrases refer to section 16.
<1%
4 First aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact In case of contact with skin, remove mechanically, wash thoroughly with plenty of soap and water. Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water. Avert vomiting. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · Information for doctor · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. RU
(Contd. on page 4)
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 3)
5 Firefighting measures · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · Methods and material for containment and cleaning up: Pick up the product mechanically, avoid dust formation. · Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. 7 Handling and storage · Handling · Precautions for safe handling Prevent formation of dust. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep container tightly sealed. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Components with critical values that require monitoring at the workplace: 100-51-6 benzyl alcohol (2,5-10%) PDK (Russia) Long-term value: 5 mg/m³ п; +; 112-24-3 triethylenetetramine (2,5-10%) PDK (Russia) Long-term value: 0,3 mg/m³ п+а; A, +; 13463-67-7 titanium dioxide (<1%) PDK (Russia) Long-term value: 10 mg/m³ a; Ф; (Contd. on page 5) RU
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 4)
· Regulatory information PDK (Russia): ÃÍ 2.2.5.3532-18 Ïðåäåëüíî äîïóñòèìûå êîíöåíòðàöèè (ÏÄÊ) âðåäíûõ âåùåñòâ â âîçäóõå ðàáî÷åé çîíû · Additional information: The lists that were valid during the compilation were used as basis. · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye protection: Suitable eye protection: Basket goggles. (DIN EN 166) Suitable safety goggles in accordance with DIN EN 166. · Body protection: Apron Protective work clothing. Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. 9 Physical and chemical properties · General Information · Appearance: · Form: · Colour: · Smell: · Odour threshold: · pH-value:
Pasty like sand Characteristic Not determined. Mixture is non-soluble (in water). (Contd. on page 6) RU
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 5)
· Change in condition · Melting point/freezing point: Not determined · Initial boiling point and boiling range: >100 °C not apply · Flash point: >100 °C · Inflammability (solid, gaseous) Not determined. · Decomposition temperature: Not determined. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Critical values for explosion: · Lower: Not determined. · Upper: Not determined. · Steam pressure: Not applicable. · Density at 20 °C 1,8 g/cm³ bulk density · Relative density Not determined. · Vapour density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with · Water: Unsoluble · Partition coefficient: n-octanol/water: Not determined. · Viscosity: · dynamic: Not applicable. · kinematic: Not applicable. · Other information · Particle characteristics · Physical state
Not determined. Solid material.
10 Stability and reactivity · Reactivity No further relevant information available. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known 11 Toxicological information · Information on toxicological effects · Acute toxicity May be harmful if swallowed. · LD/LC50 values that are relevant for classification: 100-51-6 benzyl alcohol Oral LD50 1.200 mg/kg (ATE) 1.040 mg/kg (mouse) 1.620 mg/kg (rats) Dermal LD50 >2.000 mg/kg (rabbit) Inhalative LC50 4,178 mg/l (rats) (OECD 403) 112-24-3 triethylenetetramine Oral LD50 1.600 mg/kg (mouse) 2.500 mg/kg (rabbit) (Contd. on page 7) RU
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 6)
Dermal
LD50
1.716 mg/kg (rats) 1.465 mg/kg (rabbit)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1.030 mg/kg (ATE) 1.030 mg/kg (rats) (OECD 401) Dermal LD50 1.840 mg/kg (rabbit) >2.000 mg/kg (rats) Inhalative LC50/4 h >5,01 mg/l (rats) (OECD 403) 68609-08-5 Reaction products of 3-aminomethyl-3,5,5-trimethylcyclohexylamine with 2,2'-[(1methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Oral LD50 >300 mg/kg (rats) (OECD 423) Dermal LD50 >2.000 mg/kg (rats) (OECD 402) 38294-69-8 Phenol, 4,4-(1-methylethylidene)bis-, polymer with N,N-bis(2-aminoethyl)-1,2ethanediamine and (chloromethyl)oxirane Oral LD50 200-2.000 mg/kg (rats) Dermal LD50 10.000 mg/kg (rabbit) 13463-67-7 titanium dioxide Oral LD50 >5.000 mg/kg (rats) Dermal LD50 >10.000 mg/kg (rabbit) Inhalative LC50/4 h 6,8 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Suspected of causing cancer. Route of exposure: Inhalation. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · Additional toxicological information: Sensitizing 12 Ecological information · Toxicity · Aquatic toxicity: 100-51-6 benzyl alcohol EC 50 390 mg/kg /(24h) (Pseudomas putida) LC50/96h 460 mg/l (Pimephales promelas) (EPA OPP 72-1) 645 mg/l (orfe) EC10 >658 mg/l /16h (Pseudomas putida) (DIN 38412) EC50 (48h) 230 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) (static) 770 mg/l (Pseudokirchneriella subcapitata) (OECD 201) NOEC 51 mg/l /21d (Daphnia magna) (OECD 211) 310 mg/l (Pseudokirchneriella subcapitata) (OECD 201) 112-24-3 triethylenetetramine LC50/96h 330 mg/l (Pimephales promelas) (Contd. on page 8) RU
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 7)
EC50 (48h) EC/LC50 (72h) EC/LC50
<500 mg/l (orfe) 31 mg/l (Daphnia magna) 20 mg/l (Grünalge (Scenedesmus subspicatus)) 2,5 mg/l /16h (Grünalge (Scenedesmus subspicatus))
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine LC50/96h 110 mg/l (Leuciscus idus) (OECD 203) EC50 (48h) 23 mg/l (Daphnia magna) (OECD TG 202) EC/10/18h 1.120 mg/l (Pseudomas putida) (Bringmann and Kühn 10, 87-98 (1977)) ERC50 >50 mg/l (Scenedesmus subspicatus) (EG 88/302 (72h)) 68609-08-5 Reaction products of 3-aminomethyl-3,5,5-trimethylcyclohexylamine with 2,2'-[(1methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane LC50/96h 1,62 mg/l (Brachydanio rerio) (OECD 203) EC50 (48h) 1,59 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) 3,13 mg/l (Pseudokirchneriella subcapitata) (OECD 201) NOEC 0,705 mg/l (Daphnia magna) (OECD 202) 2,07 mg/l (Pseudokirchneriella subcapitata) (OECD 201) 0,964 mg/l (Brachydanio rerio) (OECD 203) 13463-67-7 titanium dioxide LC 0 48 mg/l (Leuciscus idus) EC0 30 mg/l (Daphnia magna) 24 mg/l (Pseudomonas flourescens) · Persistence and degradability No further relevant information available. · Behaviour in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Ecotoxical effects: 112-24-3 triethylenetetramine EC 50 800 mg/l (activated sludge bacteria) 137 mg/l (Pseudomas putida) · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. RU
(Contd. on page 9)
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 8)
14 Transport information · UN-Number · ADR, IMDG, IATA
Void
· UN proper shipping name · ADR, IMDG, IATA
· Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· Packing group · ADR, IMDG, IATA
· Environmental hazards: · Marine pollutant:
No
· Special precautions for user
Not applicable.
· Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation":
15 Regulatory information · GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). · Hazard pictograms GHS05, GHS07, GHS08 · Signal word Danger · Hazard-determining components of labelling: benzyl alcohol 3-aminomethyl-3,5,5-trimethylcyclohexylamine titanium dioxide triethylenetetramine Phenol, 4,4-(1-methylethylidene)bis-, polymer with N,N-bis(2-aminoethyl)-1,2-ethanediamine and (chloromethyl)oxirane · Hazard statements May be harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of causing cancer. Route of exposure: Inhalation. · Precautionary statements Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. RU
(Contd. on page 10)
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Trade name: ASODUR-K4031 (B-Komp.) (Contd. of page 9)
16 Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H333 May be harmful if inhaled. H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Acute Tox. 5: Acute toxicity – Category 5 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Serious eye damage/irritation – Category 2A: Serious eye damage/eye irritation – Category 2A Skin Sens. 1: Skin sensitisation – Category 1 Carc. 2: Carcinogenicity – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 RU