59.1.3
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Safety data sheet according to Regulation (EC) No 1907/2006, Article 31 Printing date 10.07.2024
Version number 30
Revision: 10.07.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-V2370 (A-Komp.) · UFI: MQG0-T02P-R00N-VKEW · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning (Contd. on page 2) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 1)
· Hazard-determining components of labelling: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane oxirane, mono[(C12-14-alkyloxy)methyl] derivs Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol phenol · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. · Additional information: EUH205 Contains epoxy constituents. May produce an allergic reaction. EUH211 Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight 700. · Dangerous components: CAS: 1675-54-3 EINECS: 216-823-5 Index number: 603-073-00-2
2,2'-[(1-methylethylidene)bis(4,1phenyleneoxymethylene)]bisoxirane Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Specific concentration limits: Skin Irrit. 2; H315: C ≥ 5 % Eye Irrit. 2; H319: C ≥ 5 %
10-25%
CAS: 38640-62-9 EINECS: 254-052-6 Reg.nr.: 01-2119565150-48XXXX
Diisopropylnaphtalene Asp. Tox. 1, H304;
CAS: 9003-36-5 NLP: 500-006-8
Formaldehyde, oligomeric reaction products with 1chloro-2,3-epoxypropane and phenol Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Skin Sens. 1, H317
Aquatic Chronic 1, H410
CAS: 61788-44-1 phenol EINECS: 262-975-0 Aquatic Chronic 2, H411; Reg.nr.: 01-2119980970-27-xxxx Sens. 1, H317
2.5-10%
2.5-10% Skin Irrit. 2, H315; Skin
oxirane, mono[(C12-14-alkyloxy)methyl] derivs 2.5-10% CAS: 68609-97-2 EINECS: 271-846-8 Repr. 1A, H360F; Skin Irrit. 2, H315; Skin Sens. 1, Index number: 603-103-00-4 H317, EUH205 Reg.nr.: 01-2119485289-22-0000 (Contd. on page 3) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 2)
· Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Don't use solvents to clean the skin. Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Collect contaminated fire fighting water separately. It must not enter drains. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. (Contd. on page 4) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 3)
Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Recommended storage temperature: 10 - 30°C Keep/store only in the original container. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (10-25%) MAK (Germany) vgl. Abschn. IIb · DNELs Inhalative DNEL mg/mg³ (rats) · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. (Contd. on page 5) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 4)
· Hand protection Treat all uncovered body parts with fat-free or low-fat (oil in water emulsion) skin protection cream. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves When handling chemical substances, only chemical protective gloves with a CE mark including a four-digit test number may be worn. The design of chemical protective gloves must be selected depending on the concentration and quantity of hazardous substances in the workplace. It is recommended It is recommended to clarify the chemical resistance of the above-mentioned protective gloves for special applications with the glove manufacturer. Recommendation according to EN 374: For short-term work or as splash protection: Gloves made of butyl rubber/nitrile rubber (0.4 mm), Change and dispose of contaminated gloves immediately. Change and dispose of contaminated gloves immediately. For permanent product contact: Viton gloves (0.4 mm) Penetration time >30 min. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Suitable eye protection: Basket goggles. (DIN EN 166) · Body protection: Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Pigmented · Smell: weak · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: 0.4 % (V) · Upper: 4.67 % (V) · Flash point: >93 °C · Auto-ignition temperature: > 300 °C · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 6,300 mPas (Contd. on page 6) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 5)
· Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Not miscible or difficult to mix Not determined. 0.003 hPas (20°) 1.42 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent content: · Solids content: 0.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known ENG
(Contd. on page 7)
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 6)
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Oral LD50 >15,000 mg/kg (rats) Dermal LD50 23,000 mg/kg (Kan) 38640-62-9 Diisopropylnaphtalene Oral LD50 >4,000 mg/kg (rats) (OECD 401) Dermal LD50 >4,000 mg/kg (rats) (OECD 402) 9003-36-5 Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 61788-44-1 phenol Oral LD50 >2,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >4,500 mg/kg (rabbit) · Specific symptoms in biological assay: 38640-62-9 Diisopropylnaphtalene NOAEL ~170 mg/kg /bw/day (rats) ((6 months)) · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · Additional toxicological information: Sensitizing · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane LC50/96h 2 mg/l (for) EC50 (48h) (static) 1.8 mg/l (Daphnia magna) ERC50 (static) 11 mg/l /72h (Scenedesmus capricornutum) IC50 >42.6 mg/l /18h (bacterial toxicity) (Contd. on page 8) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 7)
38640-62-9 Diisopropylnaphtalene LL50 1.7 mg/l /48h (Daphnia magna) (OECD 202) 9003-36-5 Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol LC50/96h 2.54 mg/l (fish toxicity) EC50 (48h) 2.55 mg/l (Daphnia magna) EC/LC50 (72h) 1.8 mg/l (algae toxicity) 61788-44-1 phenol EC50 (48h) 1-10 mg/l (Daphnia magna) EC/LC50 (72h) 3.14 mg/l (Scenedesmus subspicatus) LL50 14.8 mg/l (fish toxicity) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs LC50/96h >5,000 mg/l (rainbow trout) EC50 (48h) (static) 7.2 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) 844 mg/l (algae toxicity) IC50 (static) >100 mg/l /3h (activated sludge bacteria) (OECD 209) NOEC 500 mg/l /72h (Pseudokirchneriella subcapitata) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: The mixture contains the following substances that fulfil the PBT criteria according to REACH, Annex XIII: Bis(isopropyl)naphthalene. · vPvB: The mixture contains the following substances that fulfil the vPvB criteria according to REACH, Annex XIII: Bis(isopropyl)naphthalene. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 01 00 wastes from MFSU and removal of paint and varnish (Contd. on page 9) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 8)
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances 15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED 15 01 00 packaging (including separately collected municipal packaging waste) 15 01 10* packaging containing residues of or contaminated by hazardous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700)) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700)), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700))
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number: · Stowage Category
Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F A
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. (Contd. on page 10) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 9)
· Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 E 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A(EPICHLORHYDRIN); EPOXY RESIN(NUMBER AVERAGE MOLECULAR WEIGHT<700)), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · REGULATION (EU) 2019/1021 on persistent organic pollutants (POP) None of the ingredients is listed. · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment – Annex II None of the ingredients is listed. · REGULATION (EU) 2019/1148 · Annex I - RESTRICTED EXPLOSIVES PRECURSORS (Upper limit value for the purpose of licensing under Article 5(3)) None of the ingredients is listed. · Annex II - REPORTABLE EXPLOSIVES PRECURSORS None of the ingredients is listed. · Regulation (EC) No 273/2004 on drug precursors None of the ingredients is listed. · Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H304 May be fatal if swallowed and enters airways. (Contd. on page 11) ENG
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Trade name: ASODUR-V2370 (A-Komp.) (Contd. of page 10)
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H360F May damage fertility. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. EUH205 Contains epoxy constituents. May produce an allergic reaction. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) · Contact: Department EHS (Environment-Health-Safety) Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Repr. 1A: Reproductive toxicity – Category 1A Asp. Tox. 1: Aspiration hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 ENG