59.1.3
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Safety data sheet according to Regulation (EC) No 1907/2006, Article 31 Printing date 10.07.2024
Version number 25 (replaces version 24)
Revision: 10.07.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-V2370 (B-Komp.) · UFI: A140-R08K-T005-WFRC · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Hardener component · Uses advised against Applications not mentioned above are not recommended. · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1B Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS07 Acute Tox. 4 Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H332 Harmful if inhaled. H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. (Contd. on page 2) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 1)
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: benzyl alcohol 4,4'-Isopropylidendiphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction products with 3-aminomethyl-3,5,5-trimethylcyclohexylamine m-phenylenebis(methylamine) · Hazard statements H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/. · Additional information: EUH071 Corrosive to the respiratory tract. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Hardener, aminformulation · Dangerous components: CAS: 100-51-6 EINECS: 202-859-9 Index number: 603-057-00-5 CAS: 38294-64-3 NLP: 500-101-4
benzyl alcohol 25-50% Acute Tox. 3, H331; Acute Tox. 4, H302; Eye Irrit. 2, H319; Skin Sens. 1B, H317 ATE: LD50 oral: 1,200 mg/kg 4,4'-Isopropylidendiphenol, oligomeric reaction products 25-50% with 1-chloro-2,3-epoxypropane, reaction products with 3aminomethyl-3,5,5-trimethylcyclohexylamine Skin Corr. 1B, H314; Eye Dam. 1, H318; Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 1477-55-0 m-phenylenebis(methylamine) EINECS: 216-032-5 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Reg.nr.: 01-2119480150-50-xxxx Tox. 4, H332; Skin Sens. 1, H317; Aquatic Chronic 3, H412 · Additional information For the wording of the listed hazard phrases refer to section 16.
10-25%
ENG
(Contd. on page 3)
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. (Contd. on page 4) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 3)
· 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralising agent. Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in the original container. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Recommended storage temperature 10 - 30°C Store under dry conditions. Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 100-51-6 benzyl alcohol (25-50%) AGW (Germany) Long-term value: 22 mg/m³, 5 ppm 2(I);DFG, H, Y, 11 1477-55-0 m-phenylenebis(methylamine) (10-25%) MAK (Germany) als Dampf und Aerosol;vgl.Abschn.IV · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Not necessary if room is well-ventilated. (Contd. on page 5) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 4)
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves When handling chemical substances, only chemical protective gloves with a CE mark including a four-digit test number may be worn. The design of chemical protective gloves must be selected depending on the concentration and quantity of hazardous substances in the workplace. It is recommended It is recommended to clarify the chemical resistance of the above-mentioned protective gloves for special applications with the glove manufacturer. Recommendation according to EN 374: For short-term work or as splash protection protection: Gloves made of butyl rubber/nitrile rubber (0.4 mm), Change and dispose of contaminated gloves immediately. Change and dispose of contaminated gloves immediately. For permanent product contact: Viton gloves (0.4 mm) Penetration time >30 min. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Suitable eye protection: Basket goggles. (DIN EN 166) · Body protection: Apron Acid resistant protective clothing Alkaline resistant protective clothing Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Transparent · Smell: Amine-like · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: 1.2 % (V) · Upper: 13 % (V) · Flash point: 94 °C · Decomposition temperature: Not determined. (Contd. on page 6) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 5)
· pH · Viscosity: · Kinematic viscosity · dynamic at 20 °C: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Mixture is non-soluble (in water). Not determined. 100 mPas Not miscible or difficult to mix Not determined. 0.027 hPas (20°) 1.03 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent content: · Solids content: 0.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 7) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 6)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Harmful if swallowed or if inhaled. · LD/LC50 values that are relevant for classification: 100-51-6 benzyl alcohol Oral LD50 1,200 mg/kg (ATE) 1,040 mg/kg (mouse) 1,620 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rabbit) Inhalative LC50 4.178 mg/l (rats) (OECD 403) 1477-55-0 m-phenylenebis(methylamine) Oral LD50 930 mg/kg (rats) (OECD 401) Dermal LD50 >3,100 mg/kg (rabbit) (OECD 402) · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 100-51-6 benzyl alcohol EC 50 390 mg/kg /(24h) (Pseudomas putida) LC50/96h 460 mg/l (Pimephales promelas) (EPA OPP 72-1) 645 mg/l (orfe) EC10 >658 mg/l /16h (Pseudomas putida) (DIN 38412) EC50 (48h) 230 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) (static) 770 mg/l (Pseudokirchneriella subcapitata) (OECD 201) NOEC 51 mg/l /21d (Daphnia magna) (OECD 211) 310 mg/l (Pseudokirchneriella subcapitata) (OECD 201) 1477-55-0 m-phenylenebis(methylamine) LC50/96h 87.6 mg/l (fish toxicity) >100 mg/l (for) >100 mg/l (Danio rerio) EC50 (48h) 15.2 mg/l (Daphnia magna) EC/LC50 (72h) 20.3 mg/l (algae toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. (Contd. on page 8) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 7)
· 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. Danger to drinking water if even small quantities leak into soil. Harmful to aquatic organisms SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES 07 02 00 wastes from the MFSU of plastics, synthetic rubber and man-made fibres 07 02 99 wastes not otherwise specified HP6 Acute Toxicity HP8 Corrosive HP13 Sensitising HP14 Ecotoxic · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA
UN2735 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), ISOPHORONEDIAMINE) AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), ISOPHORONEDIAMINE)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class
8 Corrosive substances. (Contd. on page 9) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 8)
· Label
8
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups · Stowage Category · Segregation Code
Warning: Corrosive substances. 80 F-A,S-B (SGG18) Alkalis A SG35 Stow "separated from" SGG1-acids
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 E 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (M-PHENYLENEBIS(METHYLAMINE), ISOPHORONEDIAMINE), 8, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · REGULATION (EU) 2019/1021 on persistent organic pollutants (POP) None of the ingredients is listed. · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment – Annex II None of the ingredients is listed. · REGULATION (EU) 2019/1148 · Annex I - RESTRICTED EXPLOSIVES PRECURSORS (Upper limit value for the purpose of licensing under Article 5(3)) None of the ingredients is listed. · Annex II - REPORTABLE EXPLOSIVES PRECURSORS None of the ingredients is listed. · Regulation (EC) No 273/2004 on drug precursors None of the ingredients is listed. (Contd. on page 10) ENG
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Trade name: ASODUR-V2370 (B-Komp.) (Contd. of page 9)
· Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors None of the ingredients is listed. · 15.2 Chemical safety assessment: A chemical safety assessment has been carried out for the following substances in this mixture: Benzyl alcohol 4,4 '-isopropylidenediphenol, oligomeric reaction product with 1-chloro-2,3-epoxypropane, reaction products with 3-aminomethyl-3,5,5-trimethylcyclohexylamine 1,3-benzenedimethanamine, m-xylylenediamine A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H412 Harmful to aquatic life with long lasting effects. · Contact: Department EHS (Environment-Health-Safety) Environment protection department. · Version number of previous version: 24 · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative ATE: Acute toxicity estimate values Acute Tox. 4: Acute toxicity – Category 4 Acute Tox. 3: Acute toxicity – Category 3 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1B: Skin sensitisation – Category 1B Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 ENG