SDS_BLANKOL-92_-_406120_(17)EN.pdf
8 页数
204.2 KB
Download
<h1>SDS_BLANKOL-92_-_406120_(17)EN.pdf</h1> <p>60.0.38</p> <p>Page 1/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: BLANKOL-92 <br />· UFI: K7R8-75YA-T101-FNMD <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture release agent <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de <br />· 1.4 Emergency telephone number: <br />Poison centre Berlin (24 hours) <br />German & English <br />Tel: ++49 (0)30/30686700 <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS08 health hazard <br />Asp. Tox. 1</p> <p>H304 May be fatal if swallowed and enters airways.</p> <p>Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the GB CLP regulation. <br />· Hazard pictograms GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %) <br />White spirit (incl. Petroleum 10-25%) <br />· Hazard statements <br />H304 May be fatal if swallowed and enters airways. <br />H412 Harmful to aquatic life with long lasting effects. <br />(Contd. on page 2) <br />GB</p> <p>60.0.38</p> <p>Page 2/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 1)</p> <p>· Precautionary statements <br />P273 <br />Avoid release to the environment. <br />P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations. <br />· 2.3 Other hazards Not anwendbar. <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Preparation, contains paraffinic and naphtenic hydrocarbons. <br />· Dangerous components: <br />EC number: 920-360-0 Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics 50-100% <br />(2-30 %) <br />Asp. Tox. 1, H304, EUH066 <br />White spirit (incl. Petroleum 10-25%) <br />Asp. Tox. 1, H304 <br />CAS: 61791-31-9 <br />EINECS: 263-163-9</p> <p>10-25%</p> <p>Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. <br />Repr. 2, H361d; <br />Skin Corr. 1B, H314; <br />Aquatic Chronic 1, <br />H410; <br />Acute Tox. 4, H302 <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p><1%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the packaging or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. <br />Use fire fighting measures that suit the environment. <br />· For safety reasons unsuitable extinguishing agents Water with a full water jet. <br />(Contd. on page 3) <br />GB</p> <p>60.0.38</p> <p>Page 3/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 2)</p> <p>· 5.2 Special hazards arising from the substance or mixture <br />Formation of toxic gases is possible during heating or in case of fire. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Cool endangered containers with water spray jet. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling Keep out of the reach of children <br />· Information about protection against explosions and fires: <br />Keep ignition sources away - Do not smoke. <br />Do not spray on flames or red-hot objects. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: None. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />Wash hands during breaks and at the end of the work. <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />(Contd. on page 4) <br />GB</p> <p>60.0.38</p> <p>Page 4/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 3)</p> <p>Be sure to clean skin thoroughly after work and before breaks. <br />When the material is hardened on the skin, remove it carfully mechanically. <br />· Breathing equipment: <br />Use breathing protection only when aerosol or mist is formed. <br />Filter A/P2. <br />· Hand protection <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />Gloves made of: Natural latex, polychloroprene, nitrile rubber. <br />(Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Not suitable are gloves made of the following materials: <br />Leather gloves <br />Strong gloves <br />· Eye/face protection <br />If there a possibility of splashing, it is necessary to carry <br />a full closeable protection on the skin. <br />Suitable safety goggles in accordance with DIN EN 166. <br />· Body protection: Protective work clothing. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Liquid <br />· Colour: <br />Clear <br />· Smell: <br />Weak, characteristic <br />· Odour threshold: <br />Not determined. <br />· Melting point/freezing point: <br />Not determined <br />· Boiling point or initial boiling point and <br />boiling range <br />182 °C <br />· Flammability <br />Not applicable. <br />· Lower and upper explosion limit <br />· Lower: <br />Not determined. <br />· Upper: <br />Not determined. <br />· Flash point: <br />65 °C <br />· Auto-ignition temperature: <br />240 °C <br />· Decomposition temperature: <br />Not determined. <br />· pH <br />Mixture is non-soluble (in water). <br />· Viscosity: <br />· Kinematic viscosity <br />Not determined. <br />· dynamic at 20 °C: <br />6.4 mPas <br />· Solubility <br />· Water: <br />Not miscible or difficult to mix <br />· Partition coefficient n-octanol/water (log <br />value) <br />Not determined. <br />· Steam pressure: <br />Not determined. <br />(Contd. on page 5) <br />GB</p> <p>60.0.38</p> <p>Page 5/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 4)</p> <p>· Density and/or relative density <br />· Density at 20 °C <br />· Relative density <br />· Vapour density</p> <p>0.811 g/cm³ <br />Not determined. <br />Not determined.</p> <p>· 9.2 Other information <br />· Appearance: <br />· Form: <br />Fluid <br />· Important information on protection of health <br />and environment, and on safety. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. <br />· Solvent separation test <br />· Organic solvents: <br />18.0 % <br />· Change in condition <br />· Evaporation rate <br />Not determined. <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids <br />· Flammable solids <br />· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %) <br />Oral <br />LD50 >4,150 mg/kg (rats) (OECD 423) <br />(Contd. on page 6) <br />GB</p> <p>60.0.38</p> <p>Page 6/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 5)</p> <p>Dermal LD50 >2,000 mg/kg (rats) (OECD 402) <br />White spirit (incl. Petroleum 10-25%) <br />Oral <br />LD50 >5,000 mg/kg (rats) (OECD 401) <br />Dermal LD50 >5,000 mg/kg (rabbit) (OECD 402) <br />61791-31-9 Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. <br />Oral <br />LD50 1,500 mg/kg (rats) (OECD 425) <br />· Primary irritant effect: No irritant action known. <br />· Skin corrosion/irritation It is possible to irritate the skin. <br />· Serious eye damage/irritation Irritate-effect is possible. <br />· Aspiration hazard May be fatal if swallowed and enters airways. <br />· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed. <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />White spirit (incl. Petroleum 10-25%) <br />EL 50 <br />>1,000 mg/l /48h (Daphnia magna) (OECD 202) <br />>1,000 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />LL50 <br />>1,000 mg/l /48h (Daphnia magna) (OECD 202) <br />>1,000 mg/l /48h (rainbow trout) (OECD 203) <br />61791-31-9 Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. <br />EC 50 <br />>0.01-0.1 mg/kg /72h (Pseudokirchneriella subcapitata) (OECD 201) <br />LC50/96h 0.1 mg/l (zebra danio) (OECD 203) <br />EC50 (48h) >0.01-0.1 mg/l (Daphnia magna) (OECD 211) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Endocrine disrupting properties <br />The product does not contain substances with endocrine disrupting properties. <br />· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />(Contd. on page 7) <br />GB</p> <p>60.0.38</p> <p>Page 7/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 6)</p> <p>· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable.</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Poisons Act <br />· Regulated explosives precursors <br />None of the ingredients is listed. <br />· Regulated poisons <br />None of the ingredients is listed. <br />· Reportable explosives precursors <br />None of the ingredients is listed. <br />· Reportable poisons <br />None of the ingredients is listed. <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H302 <br />Harmful if swallowed. <br />H304 <br />May be fatal if swallowed and enters airways. <br />H314 <br />Causes severe skin burns and eye damage. <br />H361d Suspected of damaging the unborn child. <br />H410 <br />Very toxic to aquatic life with long lasting effects. <br />EUH066 Repeated exposure may cause skin dryness or cracking. <br />· Department issuing data specification sheet: Environment protection department. <br />(Contd. on page 8) <br />GB</p> <p>60.0.38</p> <p>Page 8/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 25.02.2025</p> <p>Version number 17 (replaces version 16)</p> <p>Revision: 25.02.2025</p> <p>Trade name: BLANKOL-92 <br />(Contd. of page 7)</p> <p>· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Skin Corr. 1B: Skin corrosion/irritation – Category 1B <br />Repr. 2: Reproductive toxicity – Category 2 <br />Asp. Tox. 1: Aspiration hazard – Category 1 <br />Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 <br />Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3</p> <p>· * Data compared to the previous version altered. <br />GB</p>
