59.1.19
Page 1/9
Safety data sheet according to UK REACH Printing date 25.09.2024 *
Version number 20 (replaces version 19)
Revision: 25.09.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-RB400 (B-Komp.) · UFI: E4K7-TKU9-700N-91KH · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Sealing · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008
Skin Sens. 1 H317 May cause an allergic skin reaction. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: 2-methyl-2H-isothiazol-3-one reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one [EC no. 220-239-6] (3:1) Tetramethylolacetylenediurea · Hazard statements H317 May cause an allergic skin reaction. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 25.09.2024
Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 1)
P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Water-based Dispersion of Styrolacrylate. · Dangerous components: CAS: 5395-50-6
0-<0.5%
Tetramethylolacetylenediurea Skin Sens. 1, H317
CAS: 2682-20-4 2-methyl-2H-isothiazol-3-one 0-<0.06% EINECS: 220-120-9 Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 2, Index number: 613-088-00-6 H330; Skin Corr. 1B, H314; Eye Dam. 1, H318; Aquatic Acute 1, H400 (M=10); Skin Sens. 1A, H317, EUH071 Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.0015 % CAS: 2634-33-5 1,2-benzisothiazol-3(2H)-one EINECS: 220-120-9 Acute Tox. 2, H330; Eye Dam. 1, H318; Aquatic Index number: 613-088-00-6 Acute 1, H400; Acute Tox. 4, H302; Skin Irrit. 2, H315; Skin Sens. 1, H317 ATE: LD50 oral: 450 mg/kg LC50/4 h inhalative: 0.21 mg/l Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.036 %
<0.005%
CAS: 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one 0-<0.005% EC number: 611-341-5 [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC Index number: 613-167-00-5 no. 220-239-6] (3:1) Acute Tox. 3, H301; Acute Tox. 2, H310; Acute Tox. 2, H330; Skin Corr. 1C, H314; Eye Dam. 1, H318; Aquatic Acute 1, H400 (M=100); Aquatic Chronic 1, H410 (M=100); Skin Sens. 1A, H317, EUH071 Specific concentration limits: Skin Corr. 1C; H314: C ≥ 0.6 % Skin Irrit. 2; H315: 0.06 % ≤ C < 0.6 % Eye Dam. 1; H318: C ≥ 0.6 % Eye Irrit. 2; H319: 0.06 % ≤ C < 0.6 % Skin Sens. 1A; H317: C ≥ 0.0015 % · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. (Contd. on page 3) GB
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 2)
Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Product is inflammable during water-component is existing. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. GB
(Contd. on page 4)
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 3)
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Gloves made of: Natural latex, polychloroprene, nitrile rubber. (Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves (Contd. on page 5) GB
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 4)
· Eye/face protection Safety glasses recommended during refilling. Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: White · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: Not applicable · Decomposition temperature: Not determined. · pH at 20 °C 6.5 · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 2,200 mPas · Solubility · Water: miscible · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density at 20 °C 1.03 g/cm³ · Relative density Not determined. · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent content: · Organic solvents: 0% · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids
Void Void Void Void Void Void Void (Contd. on page 6) GB
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 5)
· Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 5395-50-6 Tetramethylolacetylenediurea Oral LD50 >5,000 mg/kg (rats) (OECD 401) 2682-20-4 2-methyl-2H-isothiazol-3-one Oral LD50 120 mg/kg (rats) (EPA OPPTS 870.1100) Dermal LD50 242 mg/kg (rats) (OECD 402) 2634-33-5 1,2-benzisothiazol-3(2H)-one Oral LD50 450 mg/kg (ATE) 670 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) Inhalative LC50/4 h 0.21 mg/l (ATE) 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) Oral LD50 64 mg/kg (rats) Dermal LD50 87.12 mg/kg (Kan) Inhalative LC50/4 h 0.33 mg/l (rats) · Primary irritant effect: No irritant action known. · Serious eye damage/irritation Irritate-effect is possible. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. GB
(Contd. on page 7)
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 6)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 2682-20-4 2-methyl-2H-isothiazol-3-one LC50 (48h) 0.934 mg/l (Daphnia magna) (OECD 202) LC50/96h 4.77 mg/l (rainbow trout) (OECD 203) EC/LC50 (72h) 0.103 mg/l (algae toxicity) (OECD 201) NOEC 0.04 mg/l (Daphnia magna) ((21 d)) 2.1 mg/l (Pimephales promelas) ((33 d)) 2634-33-5 1,2-benzisothiazol-3(2H)-one EC 50 0.11 mg/kg /72h (Selenastrum capricornutum) (OECD 201) LC50/96h 2.2 mg/l (rainbow trout) (OECD 203) EC50 (48h) 3.27 mg/l (Daphnia (acute) toxicity) (OECD 202) NOEC 1.2 mg/l /21d (Daphnia magna) (OECD 211) 0.04 mg/l /72h (Selenastrum capricornutum) (OECD 201) 0.21 mg/l /28d (rainbow trout) (OECD 215) 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) LC50 (48h) 0.16 mg/l (Daphnia magna) (vgl OECD 202) LC50/96h 0.19 mg/l (rainbow trout) (vgl. OECD 203) ERC50 0.0052 mg/l (algae toxicity) (48h, OECD 201) NOEC 0.1 mg/l (Daphnia magna) (21 d) 0.05 mg/l (rainbow trout) (14 d) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation This product must be disposed as dangerous waste. Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. GB
(Contd. on page 8)
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 7)
SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H301 Toxic if swallowed. H302 Harmful if swallowed. H310 Fatal in contact with skin. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract. (Contd. on page 9) GB
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Trade name: AQUAFIN-RB400 (B-Komp.) (Contd. of page 8)
· Department issuing data specification sheet: Department EHS (Environment-Health-Safety) Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative ATE: Acute toxicity estimate values Acute Tox. 3: Acute toxicity – Category 3 Acute Tox. 4: Acute toxicity – Category 4 Acute Tox. 2: Acute toxicity – Category 2 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Corr. 1C: Skin corrosion/irritation – Category 1C Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· * Data compared to the previous version altered. GB