59.1.3
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Safety data sheet according to UK REACH Printing date 24.07.2024 *
Version number 17
Revision: 24.07.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-EKF (A-Komp.) · UFI: U4D0-J030-V00V-37Y6 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy resin adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 health hazard Repr. 1B
H360F May damage fertility.
Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07, GHS08 · Signal word Danger · Hazard-determining components of labelling: Epoxy Phenol Novolak Resin oxirane, mono[(C12-14-alkyloxy)methyl] derivs (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 24.07.2024
Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 1)
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Reaction products of 2,2-dimethylpropane-1,3-diol with 1-chloro-2,3-epoxypropane N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H360F May damage fertility. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Solvent free preparation based on modified Epoxy-resins. · Dangerous components: EC number: 701-263-0
Epoxy Phenol Novolak Resin Aquatic Chronic 2, H411; 1, H317
2.5-10% Skin Irrit. 2, H315; Skin Sens.
2.5-10% CAS: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] EINECS: 216-823-5 bisoxirane Index number: 603-073-00-2 Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Specific concentration limits: Skin Irrit. 2; H315: C ≥ 5 % Eye Irrit. 2; H319: C ≥ 5 % EC number: 701-333-0
Reaction products of 2,2-dimethylpropane-1,3-diol with 1chloro-2,3-epoxypropane Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic Chronic 3, H412
2.5-10%
CAS: 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs EINECS: 271-846-8 Repr. 1B, H360F; Skin Irrit. 2, H315; Skin Sens. 1, Index number: 603-103-00-4 H317, EUH205
<2.5%
CAS: 123-26-2 N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) EINECS: 204-613-6 Skin Sens. 1B, H317; Aquatic Chronic 3, H412 · Additional information For the wording of the listed hazard phrases refer to section 16.
<0.5%
GB
(Contd. on page 3)
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Instantly rinse with water. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. (Contd. on page 4) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 3)
· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures Clean skin only with cleaning agent especially for epoxy resin. Don't use solvent for skin cleaning! Clean clothes which are contaminate with epoxi resin before unsing again. The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. (Contd. on page 5) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 4)
· Hand protection Treat all uncovered body parts with fat-free or low-fat (oil in water emulsion) skin protection cream. Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection In case of splashing use protecting basket-glasses. Suitable eye protection: Basket goggles. (DIN EN 166) · Body protection: Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: According to product specification · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: >100 °C · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic: Not determined. · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density at 20 °C 1.8 g/cm³ · Relative density Not determined. · Vapour density Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 5)
· 9.2 Other information · Appearance: · Form: Viscous · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: Epoxy Phenol Novolak Resin Oral LD50 >5,000 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Oral LD50 >15,000 mg/kg (rats) Dermal LD50 23,000 mg/kg (Kan) (Contd. on page 7) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 6)
Reaction products of 2,2-dimethylpropane-1,3-diol with 1-chloro-2,3-epoxypropane Oral LD50 3,595 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >4,500 mg/kg (rabbit) 64741-65-7 Naphtha (petroleum), heavy alkylate Oral LD50 >5,000 mg/kg (rats) (OECD 401) Dermal LD50 >5,000 mg/kg (rabbit) (OECD 402) Inhalative LC50/4 h >4,951 mg/l (rats) (OECD 403) 123-26-2 N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) Oral LD50 >2,000 mg/kg (rats) Inhalative LC50/4 h 5.05 mg/l (rats) · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Reproductive toxicity May damage fertility. · Additional toxicological information: Sensitizing · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: Epoxy Phenol Novolak Resin LC50/96h 5.7 mg/l (Leuciscus idus) EC50 (48h) 2.55 mg/l (Daphnia magna) EC50 1.8 mg/l (Selenastrum capricornutum) (OECD 201) IC50 (static) >100 mg/l /3h (activated sludge bacteria) 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane LC50/96h 2 mg/l (for) EC50 (48h) (static) 1.8 mg/l (Daphnia magna) ERC50 (static) 11 mg/l /72h (Scenedesmus capricornutum) IC50 >42.6 mg/l /18h (bacterial toxicity) Reaction products of 2,2-dimethylpropane-1,3-diol with 1-chloro-2,3-epoxypropane LC50/96h 101 mg/l (fish toxicity) (QSAR) EC50 (48h) 10-100 mg/l (Daphnia magna) EC50 (96h) 1,073.67 mg/l (algae toxicity) (QSAR) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs LC50/96h >5,000 mg/l (rainbow trout) EC50 (48h) (static) 7.2 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) 844 mg/l (algae toxicity) IC50 (static) >100 mg/l /3h (activated sludge bacteria) (OECD 209) (Contd. on page 8) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 7)
NOEC
500 mg/l /72h (Pseudokirchneriella subcapitata)
64741-65-7 Naphtha (petroleum), heavy alkylate EC/LC50 (48h) (static) >1,000 mg/l (Daphnia magna) (OECD 202) EL 50 (static) >1,000 mg/l /72h (Pseudokirchneriella subcapitata) LL50 (static) >1,000 mg/l /96h (rainbow trout) (OECD 203) NOEL 0.192 mg/l (fish toxicity) 123-26-2 N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) EC 50 >100 mg/kg /72h (algae toxicity) EL 50 >10 mg/l /48h (Daphnia magna) LL50 >10 mg/l /96h (rainbow trout) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Can be deposited with household garbage after solidification following consultation with the operator of the waste disposal facility and the pertinent authorities and under adherence to the necessary technical regulations. Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
Void (Contd. on page 9) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 8)
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H360F May damage fertility. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH205 Contains epoxy constituents. May produce an allergic reaction. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) Environment protection department. · Contact: Environment protection department. Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative (Contd. on page 10) GB
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Trade name: ASODUR-EKF (A-Komp.) (Contd. of page 9) Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1B: Skin sensitisation – Category 1B Repr. 1B: Reproductive toxicity – Category 1B Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB