59.1.3
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Safety data sheet according to UK REACH Printing date 24.07.2024 *
Version number 7 (replaces version 6)
Revision: 24.07.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-EKF (B-Komp.) · UFI: J8DP-NX1F-P3MY-U70T · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Hardener component · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG ICS GmbH Aquafinstr. 2-8 D-32760 Detmold Germany ----------------------------------------------Tel: ++49 (0)5231/953-02 Fax: ++49 (0)5231/953-390 web: www.schomburg.com · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 corrosion Skin Corr. 1A Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
Acute Tox. 4 Skin Sens. 1
H332 Harmful if inhaled. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07, GHS09 · Signal word Danger · Hazard-determining components of labelling: polyamines adduct 3-aminomethyl-3,5,5-trimethylcyclohexylamine m-phenylenebis(methylamine) Polyethylenpolyamin (Teta - Fraktion) 3,6,9 Triazaundecan, 1,11-diamin (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 24.07.2024
Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 1)
3-(2-Aminoethylamino)-propyltrimethoxysilan · Hazard statements H332 Harmful if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dusts or mists. P273 Avoid release to the environment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Hardener, aminformulation · Dangerous components: CAS: 68410-23-1 EC number: 614-452-7
polyamines adduct Eye Dam. 1, H318; Aquatic Chronic 2, H411; Irrit. 2, H315; Skin Sens. 1, H317
25-50% Skin
10-25% CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine EINECS: 220-666-8 Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, Index number: 612-067-00-9 H302; Acute Tox. 4, H312; Skin Sens. 1A, H317 ATE: LD50 oral: 1,030 mg/kg Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.001 % CAS: 1477-55-0 EINECS: 216-032-5
m-phenylenebis(methylamine) 10-25% Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 90640-67-8
Polyethylenpolyamin (Teta - Fraktion) 2.5-10% Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 90640-66-7 EINECS: 292-587-7
3,6,9 Triazaundecan, 1,11-diamin 2.5-10% Skin Corr. 1A, H314; Eye Dam. 1, H318; Aquatic Chronic 2, H411; Acute Tox. 4, H312; Skin Sens. 1, H317
CAS: 9046-10-0 EC number: 618-561-0
O,O-Bis(2-aminopropyl)polypropyleneglycol Skin Corr. 1B, H314; Eye Dam. 1, H318; Aquatic Chronic 3, H412
CAS: 1760-24-3 EINECS: 217-164-6
3-(2-Aminoethylamino)-propyltrimethoxysilan Eye Dam. 1, H318; Skin Sens. 1, H317; Aquatic Chronic 3, H412 · Additional information For the wording of the listed hazard phrases refer to section 16.
2.5-10%
<2.5%
GB
(Contd. on page 3)
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. (Contd. on page 4) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 3)
· 6.3 Methods and material for containment and cleaning up: Use neutralising agent. Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. (Contd. on page 5) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 4)
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Tightly sealed safety glasses. In case of splashing use protecting basket-glasses. Suitable eye protection: Basket goggles. (DIN EN 166) · Body protection: Acid resistant protective clothing Alkaline resistant protective clothing Apron Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Yellowish · Smell: Amine-like · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range >200 °C · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: >100 °C · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 146 mPas · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density at 20 °C 0.97 g/cm³ · Relative density Not determined. · Vapour density Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 5)
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Harmful if inhaled. · LD/LC50 values that are relevant for classification: 68410-23-1 polyamines adduct Oral LD50 >2,000 mg/kg (rats) (OECD 423 method B1) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral LD50 1,030 mg/kg (ATE) 1,030 mg/kg (rats) (OECD 401) (Contd. on page 7) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 6)
Dermal
LD50 1,840 mg/kg (rabbit) >2,000 mg/kg (rats)
1477-55-0 m-phenylenebis(methylamine) Oral LD50 930 mg/kg (rats) (OECD 401) Dermal LD50 >3,100 mg/kg (rabbit) (OECD 402) 90640-67-8 Polyethylenpolyamin (Teta - Fraktion) Oral LD50 1,716 mg/kg (rats) (OECD 401) Dermal LD50 1,465 mg/kg (Kan) (OECD 402) 90640-66-7 3,6,9 Triazaundecan, 1,11-diamin Oral LD50 3,221 mg/kg (rats) (experimental study) Dermal LD50 1,260 mg/kg (rabbit) (experimental study) 9046-10-0 O,O-Bis(2-aminopropyl)polypropyleneglycol Oral LD50 2,885.3 mg/kg (rats) (OECD 401) Dermal LD50 2,979.7 mg/kg (rabbit) Inhalative LC 50 >0.74 mg/l /8h (rats) (OECD 403) · Specific symptoms in biological assay: 9046-10-0 O,O-Bis(2-aminopropyl)polypropyleneglycol NOAEL 30 mg/kg (rats) (OECD 421) · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 68410-23-1 polyamines adduct LC50/96h 7.07 mg/l (zebra danio) (OECD 203) EC50 (3h) 314 mg/l (activated sludge bacteria) (OECD 209) EC50 5.18 mg/l /48h (Daphnia magna) (OECD 202) ERC50 4.11 mg/l (Pseudokirchneriella subcapitata) (OECD 201) NOEC 2.5 mg/l (Daphnia magna) 1.25 mg/l (Pseudokirchneriella subcapitata) 5 mg/l (zebra danio) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine LC50/96h 110 mg/l (Leuciscus idus) (OECD 203) EC50 (48h) 23 mg/l (Daphnia magna) (OECD TG 202) EC/10/18h 1,120 mg/l (Pseudomas putida) (Bringmann and Kühn 10, 87-98 (1977)) ERC50 >50 mg/l (Scenedesmus subspicatus) (EG 88/302 (72h)) 1477-55-0 m-phenylenebis(methylamine) LC50/96h 87.6 mg/l (fish toxicity) >100 mg/l (for) >100 mg/l (Danio rerio) EC50 (48h) 15.2 mg/l (Daphnia magna) (Contd. on page 8) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 7)
EC/LC50 (72h)
20.3 mg/l (algae toxicity)
9046-10-0 O,O-Bis(2-aminopropyl)polypropyleneglycol LC50/96h >15 mg/l (fish toxicity) (OECD 203) EC50 (48h) (static) 80 mg/l (Daphnia magna) (OECD 202) ERC50 (static) 15 mg/l (algae toxicity) (OECD 201) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised. Danger to drinking water if even small quantities leak into soil. Harmful to aquatic organisms SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG, IATA
UN2735 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (Polyethylenpolyamin (Teta - Fraktion), ISOPHORONEDIAMINE), ENVIRONMENTALLY HAZARDOUS AMINES, LIQUID, CORROSIVE, N.O.S. (Polyethylenpolyamin (Teta - Fraktion), ISOPHORONEDIAMINE)
· 14.3 Transport hazard class(es) · ADR, IMDG
· Class
8 Corrosive substances. (Contd. on page 9) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 8)
· Label
8
· IATA
· Class · Label
8 Corrosive substances. 8
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR):
Product contains environmentally hazardous substances: polyamines adduct Symbol (fish and tree) Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups · Stowage Category · Segregation Code
Warning: Corrosive substances. 80 F-A,S-B (SGG18) Alkalis A SG35 Stow "separated from" SGG1-acids
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 2 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (POLYETHYLENPOLYAMIN (TETA - FRAKTION), ISOPHORONEDIAMINE), 8, II, ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. (Contd. on page 10) GB
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Trade name: ASODUR-EKF (B-Komp.) (Contd. of page 9)
· Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative ATE: Acute toxicity estimate values Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB