59.1.3
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Safety data sheet according to UK REACH Printing date 24.07.2024 *
Version number 63 (replaces version 62)
Revision: 24.07.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-GBM (A-Komp.) · UFI: U9D0-J0FT-G00U-EX4A · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 health hazard Repr. 1B
H360F May damage fertility. environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07, GHS08, GHS09 · Signal word Danger (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 24.07.2024
Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 1)
· Hazard-determining components of labelling: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane oxirane, mono[(C12-14-alkyloxy)methyl] derivs Hydrocarbons Epoxy Phenol Novolak Resin · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H360F May damage fertility. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Solvent- free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight 700. · Dangerous components: CAS: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] 50-100% EINECS: 216-823-5 bisoxirane Index number: 603-073-00-2 Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Specific concentration limits: Skin Irrit. 2; H315: C ≥ 5 % Eye Irrit. 2; H319: C ≥ 5 % CAS: 71302-83-5
EC number: 701-263-0
Hydrocarbons Asp. Tox. 1, H304; Chronic 3, H412
10-25% Skin Sens. 1A, H317; Aquatic
Epoxy Phenol Novolak Resin Aquatic Chronic 2, H411; 1, H317
2.5-10% Skin Irrit. 2, H315; Skin Sens.
CAS: 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs EINECS: 271-846-8 Repr. 1B, H360F; Skin Irrit. 2, H315; Skin Sens. 1, Index number: 603-103-00-4 H317, EUH205 · Additional information For the wording of the listed hazard phrases refer to section 16.
2.5-10%
GB
(Contd. on page 3)
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Don't use solvents to clean the skin. Instantly wash with water and soap and rinse thoroughly. Instantly rinse with water. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Avoid eye- and skin contact. (Contd. on page 4) GB
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 3)
Do not breath in vapour. Keep away from ignition sources Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep containers tightly sealed. Work with fresh air supply (open windows and doors). Keep away from heat and direct sunlight. Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Do not leave open containers. Do not store in common rooms. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · DNELs 71302-83-5 Hydrocarbons Oral DNEL 0.33 mg/kg /bw/day (General population) Dermal DNEL Dermal 1.67 mg/kg /bw/day (General population) 4.7 mg/kg /bw/day (Labourers) Inhalative DNEL 0.58 mg/mg³ (General population) 3.3 mg/mg³ (Labourers) · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. (Contd. on page 5) GB
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 4)
Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures Do not take thinner to clean the skin. Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Tightly sealed safety glasses. In case of splashing use protecting basket-glasses. Suitable eye protection: Basket goggles. (DIN EN 166) · Body protection: Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Colourless · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range >200 °C · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 5)
· Flash point: · Auto-ignition temperature: · Decomposition temperature: · pH · Viscosity: · Kinematic viscosity · dynamic at 20 °C: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
130 °C 235 °C Not determined. Mixture is non-soluble (in water). Not determined. 1,588 mPas Not miscible or difficult to mix Not determined. Not determined. 1.12 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts violently with oxidizing agents Reacts with strong acids and oxidizing agents (Contd. on page 7) GB
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 6)
· 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Can react with acid and oxidizing agents. · 10.6 Hazardous decomposition products: În case of heating dangerous decomposition products can be arise. SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Oral LD50 >15,000 mg/kg (rats) Dermal LD50 23,000 mg/kg (Kan) 71302-83-5 Hydrocarbons Oral LD50 >2,000 mg/kg (rats) (OECD Prüfrichtlinie 423) Dermal LD50 >2,000 mg/kg (rats) (OECD Prüfrichtlinie 402) Epoxy Phenol Novolak Resin Oral LD50 >5,000 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (OECD 402) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >4,500 mg/kg (rabbit) · Specific symptoms in biological assay: 71302-83-5 Hydrocarbons NOAEL 1,000 mg/kg /28d (rats) (OECD Prüfrichtlinie 410) · Primary irritant effect: 71302-83-5 Hydrocarbons Dermal Haut (rabbit) (OECD Prüfrichtlinie 404) Irritation of eyes Auge (rabbit) (OECD Prüfrichtlinie 405) · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Reproductive toxicity May damage fertility. · Other information (about experimental toxicology): 71302-83-5 Hydrocarbons Amestest/Genmutation (bacterial toxicity) (OECD Prüfrichtlinie 471) · Additional toxicological information: Sensitizing · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane LC50/96h 2 mg/l (for) EC50 (48h) (static) 1.8 mg/l (Daphnia magna) (Contd. on page 8) GB
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 7)
ERC50 (static) IC50
11 mg/l /72h (Scenedesmus capricornutum) >42.6 mg/l /18h (bacterial toxicity)
71302-83-5 Hydrocarbons LC 0 5 mg/l /4h (rats) (OECD Prüfrichtlinie 403 (Aerosol)) EL 50 >100 mg/l /72h (algae toxicity) (OECD Prüfrichtlinie 201) 54 mg/l /48h (daphnia) (OECD Prüfrichtlinie 202) LL50 25.8 mg/l (fish) (OECD Prüfrichtlinie 203) Epoxy Phenol Novolak Resin LC50/96h 5.7 mg/l (Leuciscus idus) EC50 (48h) 2.55 mg/l (Daphnia magna) EC50 1.8 mg/l (Selenastrum capricornutum) (OECD 201) IC50 (static) >100 mg/l /3h (activated sludge bacteria) 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs LC50/96h >5,000 mg/l (rainbow trout) EC50 (48h) (static) 7.2 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) 844 mg/l (algae toxicity) IC50 (static) >100 mg/l /3h (activated sludge bacteria) (OECD 209) NOEC 500 mg/l /72h (Pseudokirchneriella subcapitata) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water danger class 3 (Self-assessment): extremely hazardous for water. Do not allow product to reach ground water, water bodies or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into soil. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,2'-[(1methylethylidene)bis(4,1-phenyleneoxymethylene)] (Contd. on page 9) GB
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 8)
· · IMDG
· IATA
bisoxirane, Diisopropylnaphtalene) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,2'-[(1-methylethylidene)bis(4,1phenyleneoxymethylene)]bisoxirane, Diisopropylnaphtalene), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,2'-[(1-methylethylidene)bis(4,1phenyleneoxymethylene)]bisoxirane, Diisopropylnaphtalene)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number: · Stowage Category
Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F A
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,2'-[(1METHYLETHYLIDENE)BIS(4,1PHENYLENEOXYMETHYLENE)]BISOXIRANE, DIISOPROPYLNAPHTALENE), 9, III GB
(Contd. on page 10)
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Trade name: ASODUR-GBM (A-Komp.) (Contd. of page 9)
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H360F May damage fertility. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH205 Contains epoxy constituents. May produce an allergic reaction. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (UK REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Repr. 1B: Reproductive toxicity – Category 1B Asp. Tox. 1: Aspiration hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB