SDS_ASOFLEX-AKB WAND BODEN (B-Komp.)_-_203555B_(24)EN.pdf
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<h1>SDS_ASOFLEX-AKB WAND BODEN (B-Komp.)_-_203555B_(24)EN.pdf</h1> <p>60.0.13</p> <p>Page 1/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024 <br />*</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />· UFI: D9EU-CU5Y-J502-AK4A <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Hardening agent/ Curing agent <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de <br />· 1.4 Emergency telephone number: <br />Poison centre Berlin (24 hours) <br />German & English <br />Tel: ++49 (0)30/30686700 <br />SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />GHS08 health hazard <br />Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Carc. 2 <br />H351 Suspected of causing cancer. <br />STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. <br />GHS07 <br />Acute Tox. 4 <br />Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H335 May cause respiratory irritation. <br />(Contd. on page 2) <br />GB</p> <p>60.0.13</p> <p>Page 2/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 1)</p> <p>· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the GB CLP regulation. <br />· Hazard pictograms GHS07, GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />diphenylmethane-4,4'-di-isocyanante <br />diphenylmethane-2,4'-diisocyanate <br />diphenylmethanediisocyanate,isomeres and homologues <br />diphenylmethane-2,2'-diisocyanate <br />· Hazard statements <br />H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H317 May cause an allergic skin reaction. <br />H351 Suspected of causing cancer. <br />H335 May cause respiratory irritation. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />· Precautionary statements <br />P260 <br />Do not breathe dust/fume/gas/mist/vapours/spray. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection/hearing <br />protection. <br />P284 <br />[In case of inadequate ventilation] wear respiratory protection. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· Additional information: <br />EUH204 Contains isocyanates. May produce an allergic reaction. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Preparation based on diphenylmethane diisocyanate (MDI) prepolymer. <br />· Dangerous components: <br />CAS: 101-68-8 <br />diphenylmethane-4,4'-di-isocyanante <br />25-50% <br />EINECS: 202-966-0 <br />Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; <br />Index number: 615-005-00-9 <br />Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317; STOT SE 3, H335, EUH204 <br />Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % <br />Skin Irrit. 2; H315: C ≥ 5 % <br />Resp. Sens. 1; H334: C ≥ 0.1 % <br />STOT SE 3; C ≥ 5 % <br />CAS: 5873-54-1 <br />diphenylmethane-2,4'-diisocyanate <br />25-50% <br />EINECS: 219-799-4 <br />Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; <br />Index number: 615-005-00-9 <br />Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317; STOT SE 3, H335, EUH204 <br />Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % <br />Skin Irrit. 2; H315: C ≥ 5 % <br />Resp. Sens. 1; H334: C ≥ 0.1 % <br />STOT SE 3; C ≥ 5 % <br />(Contd. on page 3) <br />GB</p> <p>60.0.13</p> <p>Page 3/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 2)</p> <p>10-25% <br />CAS: 9016-87-9 <br />diphenylmethanediisocyanate,isomeres and homologues <br />Index number: 615-005-00-9 <br />Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; <br />Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317; STOT SE 3, H335, EUH204 <br />Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % <br />Skin Irrit. 2; H315: C ≥ 5 % <br />Resp. Sens. 1; H334: C ≥ 0.1 % <br />STOT SE 3; C ≥ 5 % <br />CAS: 2536-05-2 <br />diphenylmethane-2,2'-diisocyanate <br />2.5-10% <br />EINECS: 219-799-4 <br />Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; <br />Index number: 615-005-00-9 <br />Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; <br />Skin Sens. 1, H317; STOT SE 3, H335, EUH204 <br />Specific concentration limits: Eye Irrit. 2; H319: C ≥ 5 % <br />Skin Irrit. 2; H315: C ≥ 5 % <br />Resp. Sens. 1; H334: C ≥ 0.1 % <br />STOT SE 3; C ≥ 5 % <br />CAS: 99-63-8 <br />EINECS: 202-774-7</p> <p>isophthaloyl dichloride <br />Acute Tox. 3, H331; <br />Skin Corr. 1B, H314; <br />Acute <br />Tox. 4, H312 <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />*</p> <p><0.5%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />In case of unconsciousness bring patient into stable side position for transport. <br />Supply fresh air and call for doctor for safety reasons. <br />· After skin contact <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />No administration of home remedies (milk, alcohol, oil, etc.). <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Do not induce vomiting; instantly call for medical help. <br />Show the packaging or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />After seriously exposition the patient should be 48 hours under medical supervision. <br />GB</p> <p>(Contd. on page 4)</p> <p>60.0.13</p> <p>Page 4/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 3)</p> <p>*</p> <p>SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />In case of fire toxic and harmful substances could be formed. <br />Following formations are possible: carbon monoxide, carbon dioxide, nitrogenoxide,hydrocarbon and <br />HCN. Containers can burst in case of heat. <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Cool endangered containers with water spray jet. <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray.</p> <p>*</p> <p>SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· 6.3 Methods and material for containment and cleaning up: <br />Ensure adequate ventilation. <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Do not breath in aerosole, dust and vapour. <br />Ensure good ventilation/extraction at the workplace. <br />Prevent formation of aerosols. <br />Keep out of the reach of children <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: <br />Protect against wetness and water. <br />Protect from frost <br />The Product reacts with water and CO2-Gas will be given off. <br />In tight closed containers pressure may arise and the cover can burst. <br />· Information about storage in one common storage facility: <br />Recommended storage conditions: Indoor, Temperature between 10°C-30°C <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: <br />Keep container tightly sealed. <br />Store in a locked cabinet and out of the reach of children. <br />(Contd. on page 5) <br />GB</p> <p>60.0.13</p> <p>Page 5/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 4)</p> <p>· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />101-68-8 diphenylmethane-4,4'-di-isocyanante (25-50%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />5873-54-1 diphenylmethane-2,4'-diisocyanate (25-50%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (10-25%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />2536-05-2 diphenylmethane-2,2'-diisocyanate (2.5-10%) <br />WEL Short-term value: 0.07 mg/m³ <br />Long-term value: 0.02 mg/m³ <br />Sen; as -NCO <br />· Regulatory information WEL: EH40/2020 <br />· Ingredients with biological limit values: <br />101-68-8 diphenylmethane-4,4'-di-isocyanante (25-50%) <br />BMGV 1 µmol creatinine/mol <br />Medium: urine <br />Sampling time: At the end of the period od exposure <br />Parameter: isocyanate-derived diamine <br />5873-54-1 diphenylmethane-2,4'-diisocyanate (25-50%) <br />BMGV 1 µmol creatinine/mol <br />Medium: urine <br />Sampling time: At the end of the period od exposure <br />Parameter: isocyanate-derived diamine <br />2536-05-2 diphenylmethane-2,2'-diisocyanate (2.5-10%) <br />BMGV 1 µmol creatinine/mol <br />Medium: urine <br />Sampling time: At the end of the period od exposure <br />Parameter: isocyanate-derived diamine <br />· Regulatory information BMGV: EH40/2011 <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />Wash hands during breaks and at the end of the work. <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Instantly remove any soiled and impregnated garments. <br />Avoid contact with the eyes and skin. <br />(Contd. on page 6) <br />GB</p> <p>60.0.13</p> <p>Page 6/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 5)</p> <p>Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />When the material is hardened on the skin, remove it carfully mechanically. <br />· Breathing equipment: <br />Filter A/P2. <br />In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer <br />exposure use breathing apparatus that is independent of circulating air. <br />· Hand protection <br />Hand Protection: Nitril-rubber-latex-gloves. <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min <br />Gloves made of: Nitrile rubber, butyl rubber. <br />(Category 3 chemical protective gloves, recognisable by the CE mark with four-digit test number). <br />When wearing protective gloves, cotton undergloves are recommended. <br />Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Not suitable are gloves made of the following materials: <br />Leather gloves <br />Strong gloves <br />· Eye/face protection <br />Tightly sealed safety glasses. <br />Suitable safety goggles in accordance with DIN EN 166. <br />· Body protection: <br />Protective work clothing. <br />Contaminated protection clothes must be cleaned carefully before reuse. <br />*</p> <p>SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Fluid <br />· Colour: <br />brownish <br />· Smell: <br />earthy, something musty. <br />· Odour threshold: <br />Not determined. <br />· Melting point/freezing point: <br />5-10 °C <br />· Boiling point or initial boiling point and <br />boiling range <br />Not determined <br />· Flammability <br />Not applicable. <br />· Lower and upper explosion limit <br />· Lower: <br />Not determined. <br />· Upper: <br />Not determined. <br />· Flash point: <br />>200 °C <br />· Auto-ignition temperature: <br />>400 °C <br />· Decomposition temperature: <br />ca 260 °C <br />· pH <br />Mixture reacts violently with water. <br />(Contd. on page 7) <br />GB</p> <p>60.0.13</p> <p>Page 7/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 6)</p> <p>· Viscosity: <br />· Kinematic viscosity <br />· dynamic at 20 °C: <br />· Solubility <br />· Water: <br />· Partition coefficient n-octanol/water (log <br />value) <br />· Steam pressure at 20 °C: <br />· Vapour pressure at 50 °C: <br />· Density and/or relative density <br />· Density at 20 °C <br />· Relative density <br />· Vapour density</p> <p>Not determined. <br />22.5 mPas <br />react with water <br />Not determined. <br />5 hPa <br />11 hPa <br />1.22 g/cm³ <br />Not determined. <br />Not determined.</p> <p>· 9.2 Other information <br />· Appearance: <br />· Form: <br />Fluid <br />· Important information on protection of health <br />and environment, and on safety. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. <br />· Change in condition <br />· Evaporation rate <br />Not determined. <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids <br />· Flammable solids <br />· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions <br />Exotherm reation with amines or alkohols, developes with water slowly CO2. Building of pressuer in <br />closed container. Danger of bursting! <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />(Contd. on page 8) <br />GB</p> <p>60.0.13</p> <p>Page 8/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 7)</p> <p>· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity Harmful if inhaled. <br />· LD/LC50 values that are relevant for classification: <br />Inhalative LC50/4 h <br />1.5 mg/l (acute toxicity) (Calculating method for mixture and expert <br />consulta) <br />101-68-8 diphenylmethane-4,4'-di-isocyanante <br />Oral <br />LD50 <br />>2,000 mg/kg (rats) (84/449/EWG, B.1) <br />Dermal LD50 <br />>9,400 mg/kg (rabbit) (OECD 402) <br />EC/LC50 (24h) >1,000 mg/l (Daphnia magna) (OECD 202) <br />5873-54-1 diphenylmethane-2,4'-diisocyanate <br />Oral <br />LD50 <br />>2,000 mg/kg (rats) (84/449/EWG, B.1) <br />Dermal LD50 <br />>9,400 mg/kg (Kan) (OECD 402) <br />EC/LC50 (24h) >1,000 mg/l (Daphnia magna) (OECD 202) <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />Oral <br />LD50 <br />>10,000 mg/kg (rats) (OECD 401) <br />Dermal LD50 <br />>9,400 mg/kg (rabbit) (OECD 402) <br />2536-05-2 diphenylmethane-2,2'-diisocyanate <br />Oral <br />LD50 <br />>2,000 mg/kg (rats) (84/449/EWG, B.1) <br />Dermal LD50 <br />>9,400 mg/kg (rats) (OECD 402) <br />EC/LC50 (24h) >1,000 mg/l (Daphnia magna) (OECD 202) <br />99-63-8 isophthaloyl dichloride <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) <br />Dermal LD50 <br />1,410 mg/kg (Kan) <br />Inhalative LC50/4 h <br />0.7 mg/l (rats) <br />· Primary irritant effect: <br />· Skin corrosion/irritation <br />Moderate irritated. <br />Animal Experiment shows that materials which knows as "sensitive the respiratory tract" (like <br />Diisocyanate) provoke that. <br />This result shows how important to use always protective clothing. <br />Repeat and/or longer contact can lead to a sentisize of the skin. <br />The product has an irritate-effect. <br />Causes skin irritation. <br />· Serious eye damage/irritation Causes serious eye irritation. <br />· Respiratory or skin sensitisation <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />May cause an allergic skin reaction. <br />· Carcinogenicity Suspected of causing cancer. <br />· STOT-single exposure May cause respiratory irritation. <br />· STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. <br />· Subacute to chronic toxicity: <br />This Produkt is irritant and sensitization are possible by inhalation: <br />repeated inhalation of steam-concentrations or aerosol about the mentioned limit could be cause to <br />sensitization of the respiratory tract. <br />Following symptomes could be caused amongst others: <br />Irritation of eyes, suffocoating in the chest and difficulties in breathing. <br />Symptoms may occur hours after exposition. <br />In fact of sensitization, persons could be heavily react on minimum MDI-Concentrations. <br />(Contd. on page 9) <br />GB</p> <p>60.0.13</p> <p>Page 9/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 8)</p> <p>Median lethal dose (4 hours) respirable aerosol: 490 mg/kg (rat) <br />· Additional toxicological information: Sensitizing <br />· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed. <br />*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />101-68-8 diphenylmethane-4,4'-di-isocyanante <br />LC50/96h <br />>1,000 mg/l (zebra danio) (OECD 403) <br />EC50 (3h) <br />>100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) <br />ERC50 <br />>1,640 mg/l (Scenedesmus subspicatus) ((72 h) OECD 201) <br />NOEC <br />>1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) <br />>1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) <br />>1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) <br />NOEC <br />>10 mg/l (Daphnia magna) ((21 d) OECD 202) <br />5873-54-1 diphenylmethane-2,4'-diisocyanate <br />LC50/96h <br />>1,000 mg/l (zebra danio) (OECD 203) <br />EC50 (3h) <br />>100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) <br />ERC50 <br />>1,640 mg/l (Scenedesmus subspicatus) (OECD 201 (72 h)) <br />NOEC <br />>1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) <br />>1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) <br />>1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) <br />NOEC <br />>10 mg/l (Daphnia magna) (OECD 202 (21 d)) <br />9016-87-9 diphenylmethanediisocyanate,isomeres and homologues <br />EC 50 <br />>1,000 mg/kg (dam) (OECD 202 (24 h)) <br />>1,640 mg/kg (Grünalge (Scenedesmus subspicatus)) (OECD 201) <br />LC50/96h <br />>1,000 mg/l (zebra danio) (OECD 203) <br />EC50 (3h) <br />>100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) <br />ERC50 <br />>1,640 mg/l (Grünalge (Scenedesmus subspicatus)) (OECD 201 (72 h)) <br />NOEC <br />>1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) <br />>1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) <br />>1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) <br />NOEC <br />>10 mg/l (dam) (OECD 202 (21 d)) <br />2536-05-2 diphenylmethane-2,2'-diisocyanate <br />LC50/96h <br />>1,000 mg/l (Danio rerio) (OECD 203) <br />EC/LC50 (72h) >1,640 mg/l (Scenedesmus subspicatus) (OECD 201) <br />EC50 (3h) <br />>100 mg/l (Atmungshem. von kommunalem Belebtschlamm) (OECD 209) <br />NOEC <br />>1,000 mg/kg (Avena sativa) (OECD 208 (14 d)) <br />>1,000 mg/kg (Eisenia fetida) (OECD 207 (14 d)) <br />>1,000 mg/kg (Lactuca sativa) (OECD 208 (14 d)) <br />NOEC <br />>10 mg/l (Daphnia magna) (OECD 202 (21 d)) <br />99-63-8 isophthaloyl dichloride <br />LC50/96h <br />134 mg/l (Pimephales promelas) <br />EC50 (48h) <br />>952 mg/l (Daphnia magna) <br />(Contd. on page 10) <br />GB</p> <p>60.0.13</p> <p>Page 10/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 9)</p> <p>EC50 (96h) <br />>996 mg/l (Scenedesmus capricornutum) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Endocrine disrupting properties <br />The product does not contain substances with endocrine disrupting properties. <br />· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards:</p> <p>Not applicable.</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Poisons Act <br />· Regulated explosives precursors <br />None of the ingredients is listed. <br />(Contd. on page 11) <br />GB</p> <p>60.0.13</p> <p>Page 11/11</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 16.12.2024</p> <p>Version number 24 (replaces version 23)</p> <p>Revision: 16.12.2024</p> <p>Trade name: ASOFLEX-AKB WAND + BODEN (B-Komp.) <br />(Contd. of page 10)</p> <p>· Regulated poisons <br />None of the ingredients is listed. <br />· Reportable explosives precursors <br />None of the ingredients is listed. <br />· Reportable poisons <br />None of the ingredients is listed. <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· I <br />85.5 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />*</p> <p>SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H312 <br />Harmful in contact with skin. <br />H314 <br />Causes severe skin burns and eye damage. <br />H315 <br />Causes skin irritation. <br />H317 <br />May cause an allergic skin reaction. <br />H319 <br />Causes serious eye irritation. <br />H331 <br />Toxic if inhaled. <br />H332 <br />Harmful if inhaled. <br />H334 <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H335 <br />May cause respiratory irritation. <br />H351 <br />Suspected of causing cancer. <br />H373 <br />May cause damage to organs through prolonged or repeated exposure. <br />EUH204 Contains isocyanates. May produce an allergic reaction. <br />· Department issuing data specification sheet: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Acute Tox. 3: Acute toxicity – Category 3 <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Skin Corr. 1B: Skin corrosion/irritation – Category 1B <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 <br />Resp. Sens. 1: Respiratory sensitisation – Category 1 <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />Carc. 2: Carcinogenicity – Category 2 <br />STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 <br />STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2</p> <p>· * Data compared to the previous version altered. <br />GB</p>
