60.0.38
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Safety data sheet according to UK REACH Printing date 25.02.2025
Version number 17 (replaces version 16)
Revision: 25.02.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: BLANKOL-92 · UFI: K7R8-75YA-T101-FNMD · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture release agent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Asp. Tox. 1
H304 May be fatal if swallowed and enters airways.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS08 · Signal word Danger · Hazard-determining components of labelling: Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %) White spirit (incl. Petroleum 10-25%) · Hazard statements H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. (Contd. on page 2) GB
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Trade name: BLANKOL-92 (Contd. of page 1)
· Precautionary statements P273 Avoid release to the environment. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards Not anwendbar. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Preparation, contains paraffinic and naphtenic hydrocarbons. · Dangerous components: EC number: 920-360-0 Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics 50-100% (2-30 %) Asp. Tox. 1, H304, EUH066 White spirit (incl. Petroleum 10-25%) Asp. Tox. 1, H304 CAS: 61791-31-9 EINECS: 263-163-9
10-25%
Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. Repr. 2, H361d; Skin Corr. 1B, H314; Aquatic Chronic 1, H410; Acute Tox. 4, H302 · Additional information For the wording of the listed hazard phrases refer to section 16.
<1%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Use fire fighting measures that suit the environment. · For safety reasons unsuitable extinguishing agents Water with a full water jet. (Contd. on page 3) GB
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Trade name: BLANKOL-92 (Contd. of page 2)
· 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Cool endangered containers with water spray jet. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep out of the reach of children · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Do not spray on flames or red-hot objects. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. (Contd. on page 4) GB
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Trade name: BLANKOL-92 (Contd. of page 3)
Be sure to clean skin thoroughly after work and before breaks. When the material is hardened on the skin, remove it carfully mechanically. · Breathing equipment: Use breathing protection only when aerosol or mist is formed. Filter A/P2. · Hand protection In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Gloves made of: Natural latex, polychloroprene, nitrile rubber. (Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection If there a possibility of splashing, it is necessary to carry a full closeable protection on the skin. Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: Clear · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range 182 °C · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: 65 °C · Auto-ignition temperature: 240 °C · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 6.4 mPas · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. (Contd. on page 5) GB
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Trade name: BLANKOL-92 (Contd. of page 4)
· Density and/or relative density · Density at 20 °C · Relative density · Vapour density
0.811 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent separation test · Organic solvents: 18.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %) Oral LD50 >4,150 mg/kg (rats) (OECD 423) (Contd. on page 6) GB
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Trade name: BLANKOL-92 (Contd. of page 5)
Dermal LD50 >2,000 mg/kg (rats) (OECD 402) White spirit (incl. Petroleum 10-25%) Oral LD50 >5,000 mg/kg (rats) (OECD 401) Dermal LD50 >5,000 mg/kg (rabbit) (OECD 402) 61791-31-9 Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. Oral LD50 1,500 mg/kg (rats) (OECD 425) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation It is possible to irritate the skin. · Serious eye damage/irritation Irritate-effect is possible. · Aspiration hazard May be fatal if swallowed and enters airways. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: White spirit (incl. Petroleum 10-25%) EL 50 >1,000 mg/l /48h (Daphnia magna) (OECD 202) >1,000 mg/l /72h (Pseudokirchneriella subcapitata) (OECD 201) LL50 >1,000 mg/l /48h (Daphnia magna) (OECD 202) >1,000 mg/l /48h (rainbow trout) (OECD 203) 61791-31-9 Ethanol, 2,2'-iminobis-, N-coco alkyl derivs. EC 50 >0.01-0.1 mg/kg /72h (Pseudokirchneriella subcapitata) (OECD 201) LC50/96h 0.1 mg/l (zebra danio) (OECD 203) EC50 (48h) >0.01-0.1 mg/l (Daphnia magna) (OECD 211) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 7) GB
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Trade name: BLANKOL-92 (Contd. of page 6)
· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H361d Suspected of damaging the unborn child. H410 Very toxic to aquatic life with long lasting effects. EUH066 Repeated exposure may cause skin dryness or cracking. · Department issuing data specification sheet: Environment protection department. (Contd. on page 8) GB
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Trade name: BLANKOL-92 (Contd. of page 7)
· Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Repr. 2: Reproductive toxicity – Category 2 Asp. Tox. 1: Aspiration hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB